Skip to main content
SpringerLink
Log in

Polarographic oxidation of some 5,10-dihydrophenazine derivatives

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The polarographic anode oxidation of 5-substituted dihydrophenazines in an aprotic medium and an aqueous acetone solution has one-electron or two-electron character. It was shown by means of the electronic and ESR spectra that the intermediates in the anode oxidation of dihydrophenazine and 5-methyldihydrophenazine are cation radicals and that the products of one-electron oxidation of 1,3-dinitro-5-aryl-substituted dihydrophenazines are phenazyl radicals. The final products of anode oxidation are phenazinium salts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. L. V. Varyukhina and Z. V. Pushkareva, Zh. Obshch. Khim., 26, 1740 (1956).

    Google Scholar 

  2. Yu. S. Rozum, S. B. Serebryanyi, E. F. Karaban, V. P. Chernetskii, and M. N. Dropkina, Zh. Obshch. Khim., 34, 2599 (1964).

    Google Scholar 

  3. L. L. Gordienko, Élektrokhimiya, 1, 1497 (1965).

    Google Scholar 

  4. D. N. Bailey, D. M. Hercules, and D. K. Roe, J. Electrochem. Soc., 116, 190 (1969).

    Google Scholar 

  5. K. H. Hausser, A. Häbich, and V. Z. Franzen, Naturf., 16a, 836 (1961).

    Google Scholar 

  6. Z. V. Pushkareva, I. N. Noskova, and V. F. Gryazev, Khim. Geterotsikl. Soedin., No. 10, 1428 (1970).

    Google Scholar 

  7. J. Heyrovsky, and J. Kuta, Fundamentals of Polarography [Russian translation], Mir, Moscow (1965).

    Google Scholar 

  8. Y. Matsunaga and C. A. McDowell, Proc. Chem. Soc., 175 (1960).

  9. W. S. Zaugg, J. Biol. Chem., 239, 3964 (1964).

    Google Scholar 

  10. G. M. Badger, R. S. Pearce, and R. Pettit, J. Chem. Soc., No. 4, 3199 (1951).

    Google Scholar 

  11. H. H. Perkumpus, Z. Phys. Chem., No. 6, 18 (1956).

    Google Scholar 

  12. G. Cauquis and D. Serve, Tetrahedron Lett., 29, 2695 (1973).

    Google Scholar 

  13. V. I. Kravtsov, Electrode Processes in Solutions of Complex Metals [in Russian], Leningrad (1969), p. 100.

  14. J. G. M. Campbell, C. G. Le Fevre, R. J. W. Le Fevre, and E. E. Turner, J. Chem. Soc., 404 (1938).

  15. J. P. Malrieu, J. Chim. Phys., 62, 485 (1965).

    Google Scholar 

  16. F. Gerson, High-Resolution Electron Spin Resonance Spectroscopy, Wiley-Interscience (1970).

  17. A. G. Terent'ev, Master's Dissertation, Kiev (1974).

Download references

Author information

Authors and Affiliations

  1. S. M. Kirov Ural Polytechnic Institute, Sverdlovsk

    I. N. Borukhova, V. F. Gryazev, I. A. Yarysheva & Z. V. Pushkareva

Authors
  1. I. N. Borukhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. F. Gryazev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Yarysheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Z. V. Pushkareva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 548–551, April, 1976.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borukhova, I.N., Gryazev, V.F., Yarysheva, I.A. et al. Polarographic oxidation of some 5,10-dihydrophenazine derivatives. Chem Heterocycl Compd 12, 458–461 (1976). https://doi.org/10.1007/BF00480440

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00480440

Keywords

Search

Navigation