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Heterocyclic analogs of pleiadiene

XXIII. Redox disproportionation of n-substituted aceperimidones. unusually facile reduction of the C=O group

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

In the reaction of chloranil with N-monosubstituted aceperimidones, in addition to dehydrogenation of the CH2CH2 bridge, the C=O group is unexpectedly reduced, and 1-alkylaceperimidylenes are obtained. N,N′-Disubstituted aceperimidones form disubstituted aceperimidylenones under the same conditions.

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Literature cited

  1. A. F. Pozharskii, T. I. Vinokurova, and V. G. Zaletov, Khim. Geterotsikl. Soedin., No. 4, 546 (1976).

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  2. I. S. Kashparov and A. F. Pozharskii, Khim. Geterotsikl. Soedin., No. 1, 124 (1971).

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  3. A. F. Pozharskii and I. S. Kashparov, No. 6, 860 (1972).

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Authors and Affiliations

  1. Rostov State University, Rostov-on-Don

    T. I. Vinokurova & A. F. Pozharskii

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  1. T. I. Vinokurova
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  2. A. F. Pozharskii
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Additional information

See [1] for communication XXII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 545–547, April, 1976.

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Vinokurova, T.I., Pozharskii, A.F. Heterocyclic analogs of pleiadiene. Chem Heterocycl Compd 12, 455–457 (1976). https://doi.org/10.1007/BF00480439

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  • DOI: https://doi.org/10.1007/BF00480439

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