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Chemistry of Heterocyclic Compounds

, Volume 12, Issue 4, pp 421–424 | Cite as

Synthesis and three-dimensional structures of substituted 4-silyl-4-piperidols

  • N. S. Prostakov
  • A. V. Varlamov
  • V. P. Zvolinskii
  • G. I. Cherenkova
  • Butros Musa Butros
  • Maria Elena Sintra
Article
  • 22 Downloads

Abstract

1,2 5-Trimethyl-4-(methyldiphenylsilyl)- and 4-(dimethylphenyl)silyl-4-piperidols were obtained. The isomers of these piperidols of the γ series, which exist in the chair conformation, have all of their substituents, except the hydroxyl group, equatorially oriented. The isomers of the α series exist in solution in the form of an equilibrium mixture of chair and boat conformations, and all of the substituents, except the silyl grouping, are equatorially oriented in the chair conformation.

Keywords

Hydroxyl Organic Chemistry Silyl Equilibrium Mixture Chair Conformation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • N. S. Prostakov
    • 1
  • A. V. Varlamov
    • 1
  • V. P. Zvolinskii
    • 1
  • G. I. Cherenkova
    • 1
  • Butros Musa Butros
    • 1
  • Maria Elena Sintra
    • 1
  1. 1.Patrice Lumumba International-Friendship UniversityMoscow

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