Chemistry of Heterocyclic Compounds

, Volume 12, Issue 4, pp 396–398 | Cite as

Reaction of 1, 5-diketones

XIX. 2,2′-Dicyclohexanonyl sulfide: Synthesis, isomerization to a cycloketol, and conversion to perhydrophenothiazine
  • E. S. Karaulov
  • A. A. Usol'tsev
  • M. N. Tilichenko


2,2′-Dicyclohexanonyl sulfide and the isomeric 2-thiatricyclo[,8]tridecan-8-ol-13-one were synthesized by reaction of α-chlorocyclohexanone with Na2S · 9H2O. Both compounds form the same perhydrophenothiazine isomers under the conditions of the Leuckart reaction.


Sulfide Organic Chemistry Na2S Leuckart Reaction 
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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • E. S. Karaulov
    • 1
  • A. A. Usol'tsev
    • 1
  • M. N. Tilichenko
    • 1
  1. 1.Far-Eastern State UniversityVladivostok

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