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Chemistry of Heterocyclic Compounds

, Volume 12, Issue 4, pp 396–398 | Cite as

Reaction of 1, 5-diketones

XIX. 2,2′-Dicyclohexanonyl sulfide: Synthesis, isomerization to a cycloketol, and conversion to perhydrophenothiazine
  • E. S. Karaulov
  • A. A. Usol'tsev
  • M. N. Tilichenko
Article
  • 30 Downloads

Abstract

2,2′-Dicyclohexanonyl sulfide and the isomeric 2-thiatricyclo[7.2.1.03,8]tridecan-8-ol-13-one were synthesized by reaction of α-chlorocyclohexanone with Na2S · 9H2O. Both compounds form the same perhydrophenothiazine isomers under the conditions of the Leuckart reaction.

Keywords

Sulfide Organic Chemistry Na2S Leuckart Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    V. I. Vysotskii, K. G. Chuprakova, and M. N. Tilichenko, Zh. Obshch. Khim., 46, 785 (1976).Google Scholar
  2. 2.
    M. N. Tilichenko and T. I. Akimova, Zh. Organ. Khim., 6, 976 (1970).Google Scholar
  3. 3.
    M. N. Tilichenko, Scientific Yearbook of Saratov State University [in Russian], (1954), p. 504.Google Scholar
  4. 4.
    M. N. Tilichenko and V. I. Vysotskii, Dokl. Akad. Nauk SSSR, Ser. Khim., 119, 1162 (1958).Google Scholar
  5. 5.
    M. N. Tilichenko and V. T. Kharchenko, 29, 2370 (1959).Google Scholar
  6. 6.
    M. N. Tilichenko and V. T. Kharchenko, 30, 2283 (1960).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • E. S. Karaulov
    • 1
  • A. A. Usol'tsev
    • 1
  • M. N. Tilichenko
    • 1
  1. 1.Far-Eastern State UniversityVladivostok

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