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Reactions of pyridinium and isoquinolinium phenacylides with nucleophiles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The hydrolysis, alcoholysis, and hydrazinolysis of N-phenacylpyridinium bromide lead to the corresponding benzoic acid derivatives. In addition, 3,6-diphenylpyridazine is formed during hydrazinolysis. The hydrolysis and alcoholysis of N-phenacylisoquinolinium bromide lead to its dimerization, whereas hydrazinolysis gives a triazinoisoquinoline derivative.

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Literature cited

  1. F. Kröhnke, Angew. Chem., 65, 605 (1953).

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  2. C. Paal and H. Schulze, Ber., 33, 3789 (1900).

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  3. V. S. Garkush-Bozhko, O. P. Shvaika, L. M. Kapkan, and S. N. Baranov, Khim. Geterotsikl. Soedin., 961 (1974).

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Authors and Affiliations

  1. Donetsk Branch, L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, USSR

    V. S. Garkusha-Bozhko, R. O. Kochkanyan, O. P. Shvaika & S. N. Baranov

Authors
  1. V. S. Garkusha-Bozhko
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  2. R. O. Kochkanyan
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  3. O. P. Shvaika
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  4. S. N. Baranov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 372–374, March, 1976.

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Garkusha-Bozhko, V.S., Kochkanyan, R.O., Shvaika, O.P. et al. Reactions of pyridinium and isoquinolinium phenacylides with nucleophiles. Chem Heterocycl Compd 12, 317–319 (1976). https://doi.org/10.1007/BF00479573

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  • DOI: https://doi.org/10.1007/BF00479573

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