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Chemistry of benzo[b]selenophene

V. Mercuration of benzo[b]selenophene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The mercuration of benzo[b]selenophene by mercuric acetate proceeds to form the 2-mercuri derivative, while 2-methyl- and 3-methylbenzo[b]selenophenes give 3-mercuri-2-methyl and 2-mercuri-3-methyl derivatives of benzo[b]selenophene, respectively. The corresponding deutero derivatives of benzo[b]selenophene were obtained by substitution of the chloromercuri group by iodine with subsequent reduction by zinc in deuterated acetic acid.

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Literature cited

  1. N. N. Magdesieva and V. A. Vdovin, Khim. Geterotsikl. Soedin., 15 (1972).

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See [1] for communication IV.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 20–23, January, 1972.

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Magdesieva, N.N., Vdovin, V.A. & Konyushkin, L.D. Chemistry of benzo[b]selenophene. Chem Heterocycl Compd 8, 18–21 (1972). https://doi.org/10.1007/BF00478481

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  • DOI: https://doi.org/10.1007/BF00478481

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