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Reaction of alkene oxides with aromatic thionylimines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The oxides of ethylene and propene, and epichlorohydrin, react with thionylanilines (ArN=S=O) in the presence of tetraethylammonium bromide catalyst at 95°–100° C to give N-arylalkeneamidosulfites, whose structures are confirmed by retrosynthesis from the corresponding N-phenylamino alcohols, and thionyl chloride, as well as by their IR spectra.

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Authors and Affiliations

  1. State Scientific Research Institute for Organochlorine Products and Acrylates, Dzerzhinsk

    V. S. Etlis, A. P. Sineokov & M. E. Sergeeva

Authors
  1. V. S. Etlis
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  2. A. P. Sineokov
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  3. M. E. Sergeeva
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Etlis, V.S., Sineokov, A.P. & Sergeeva, M.E. Reaction of alkene oxides with aromatic thionylimines. Chem Heterocycl Compd 2, 521–525 (1966). https://doi.org/10.1007/BF00477509

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  • DOI: https://doi.org/10.1007/BF00477509

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