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Heterocyclic nitro compounds

XIV. Kinetics of the nucleophilic substitution of a nitro group by a hydroxyl group in 3(5)-nitro-1,2,4-triazoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The kinetics of the substitution of a nitro group by a hydroxyl group in 1-methyl-3-nitro-,1-methyl-5-nitro-, and 3-nitro-4-methyl-1,2,4-triazoles as well as in a series of 1-methyl-3-R-5-nitro-1,2,4-triazoles were studied. The activation parameters of the reaction were determined. There is a linear correlation dependence between log k and the σm substituent constants in the investigated series.

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Authors and Affiliations

  1. Lensovet Leningrad Technological Institute, USSR

    M. S. Pevzner, V. Ya. Samarenko & L. I. Bagal

Authors
  1. M. S. Pevzner
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  2. V. Ya. Samarenko
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  3. L. I. Bagal
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Additional information

See [1] for communication XIII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 568–571, April, 1972.

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Pevzner, M.S., Samarenko, V.Y. & Bagal, L.I. Heterocyclic nitro compounds. Chem Heterocycl Compd 8, 518–521 (1972). https://doi.org/10.1007/BF00477439

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  • DOI: https://doi.org/10.1007/BF00477439

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