Abstract
The reaction of esters of 4,5-epoxy-2-hexenoic acid with ketones in the presence of acid catalysts gives 2,2,4-trialkyl-5-(2-carboalkoxyvinyl)-1,3-dioxolanes, the hydrogenation of which gives the corresponding saturated dioxolanes. The conformations and configurations of the dioxolanes obtained were studied by means of their PMR spectra.
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L. P. Glushko, N. I. Pokhodenko, M. S. Malinovskii, and É. G. Sumbaev, Zh. Organ. Khim., 7, 1591 (1971).
M. S. Malinovskii, L. P. Glushko, N. I. Pokhodenko, L. I. Kopeiko, and V. I. Avramenko, in: Chemical Structure, Properties, and Reactivities of Organic Compounds [in Russian], Kiev (1969), p. 71.
A. A. Bothner-By, Advances in Magnetic Resonance, New York-London, Vol. 1 (1965), p. 195.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 447–451, April, 1972
See [1] for communication IV.
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Samitov, Y.Y., Glushko, L.P., Malinovskii, M.S. et al. Investigations of polyfunctional oxides. Chem Heterocycl Compd 8, 408–411 (1972). https://doi.org/10.1007/BF00477408
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DOI: https://doi.org/10.1007/BF00477408