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Synthesis of 2-thiabicyclo[3.2.0]hept-3-enes by reaction of acetylene with sodium sulfide

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The previously unknown2-thiabicyclo[2.3.0]hept-3-ene and exo- and endo-6-methyl-2-thiabicyclo[3.2.0]hept-3-enes were synthesized in one step from acetylene and sodium sulfide in aqueous dimethyl disulfoxide.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    B. A. Trofimov, G. A. Kalabin, V. V. Kryuchkov, V. V. Keiko, S. V. Amosova, V. M. Bzhezovskii, V. K. Voronov, D. F. Kushnarev, V. Yu. Vitkovskii, L. I. Lavlinskaya & V. A. Pestunovich

Authors
  1. B. A. Trofimov
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  2. G. A. Kalabin
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  3. V. V. Kryuchkov
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  4. V. V. Keiko
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  5. S. V. Amosova
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  6. V. M. Bzhezovskii
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  7. V. K. Voronov
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  8. D. F. Kushnarev
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  9. V. Yu. Vitkovskii
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  10. L. I. Lavlinskaya
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  11. V. A. Pestunovich
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7. pp. 895–899, July, 1976.

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Trofimov, B.A., Kalabin, G.A., Kryuchkov, V.V. et al. Synthesis of 2-thiabicyclo[3.2.0]hept-3-enes by reaction of acetylene with sodium sulfide. Chem Heterocycl Compd 12, 745–748 (1976). https://doi.org/10.1007/BF00477002

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  • DOI: https://doi.org/10.1007/BF00477002

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