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Synthesis of the β isomers of 2,4,6-trisubstituted 1,3,5-trithianes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The condensation of bis(α-hydroxy-β,β,β-trichloroethyl) sulfide with aldehydes under acid catalysis conditions gives 2,4,6-trisubstituted 1,3,5-trithianes. The latter are realized only in the thermodynamically more favorable β forms.

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Authors and Affiliations

  1. A. M. Butlerov Scientific-Research Chemical Institute of the V. I. Ul'yanov-Lenin Kazan State University, USSR

    E. N. Klimovitskii, L. K. Yuldasheva & B. A. Arbuzov

Authors
  1. E. N. Klimovitskii
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  2. L. K. Yuldasheva
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  3. B. A. Arbuzov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1625–1626, December, 1976.

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Klimovitskii, E.N., Yuldasheva, L.K. & Arbuzov, B.A. Synthesis of the β isomers of 2,4,6-trisubstituted 1,3,5-trithianes. Chem Heterocycl Compd 12, 1336–1338 (1976). https://doi.org/10.1007/BF00476720

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  • DOI: https://doi.org/10.1007/BF00476720

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