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Investigation of the reaction of 1,2,3-trimethyl-2-phenylbenzimidazoline with dehydrogenating reagents by EPR spectroscopy

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 1,2,3-trimethyl-2-phenylbenzimidazoline with a number of reagents that manifest dehydrogenating properties with respect to benziraidazolines was studied by EPR spectroscopy. These reagents convert 1,2,3-trimethyl-2-phenylbenzimidazoline to a relatively stable cation radical. The mechanism of the dehydrogenation of benzimidazolines is discussed taking into account the established facts.

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Authors and Affiliations

  1. Scientific-Research Institute of Physical and Organic Chemistry, M. A. Suslov Rostov State University, 344090, Rostov-on-Don

    A. S. Morkovnik, E. S. Klimov, A. N. Suslov, E. P. Ivakhnenko, O. Yu. Okhlobystin & B. A. Tertov

  2. Scientific-Research Institute of the Chemistry of Free Radicals, K. A. Khetagurov North Ossetian State University, 362040, Ordzhonikidze

    A. S. Morkovnik, E. S. Klimov, A. N. Suslov, E. P. Ivakhnenko, O. Yu. Okhlobystin & B. A. Tertov

Authors
  1. A. S. Morkovnik
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  2. E. S. Klimov
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  3. A. N. Suslov
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  4. E. P. Ivakhnenko
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  5. O. Yu. Okhlobystin
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  6. B. A. Tertov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 634–638, May, 1987.

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Morkovnik, A.S., Klimov, E.S., Suslov, A.N. et al. Investigation of the reaction of 1,2,3-trimethyl-2-phenylbenzimidazoline with dehydrogenating reagents by EPR spectroscopy. Chem Heterocycl Compd 23, 525–529 (1987). https://doi.org/10.1007/BF00476380

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  • DOI: https://doi.org/10.1007/BF00476380

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