Abstract
2-Ketoindoline and 1-methyl-2-ketoindoline condense with hydroxymethylene ketones in the presence of hydrogen chloride to give pyrylium[2,3-b]indole chlorides, which can be converted to 5-(3-oxindolyl)-Δ2-pyrazolines by reaction with phenylhydrazine and to 5-(3-oxindolyl)-Δ2-isoxazolines by reaction with hydroxylamine.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1030–1032, August, 1972.
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Zhungietu, G.I., Sukhanyuk, B.P. Pyrylium[2,3-b]indole salts. Chem Heterocycl Compd 8, 932–934 (1972). https://doi.org/10.1007/BF00476316
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DOI: https://doi.org/10.1007/BF00476316