Skip to main content
Log in

Synthesis and IR spectra of 2-phenylbenzimidazole and its amino derivatives

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2-Phenylbenzimidazole and its mono and diamino derivatives were synthesized in yields up to 85% by cyclodehydration of o-aminobenzanilides in hydrochloric or sulfuric acid. The IR spectra of the compounds obtained were studied, the principal bands of the stretching and deformation vibrations of the NH and NH2 groups were assigned, and the presence of associates with a hydrogen bond was established.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. M. A. Phillips, J. Chem. Soc., 2393 (1928).

  2. B. A. Porai-Koshits and G. M. Kharkharova, Zh. Obshch. Khim., 25, 2138 (1955).

    Google Scholar 

  3. O. Kym, Ber., 32, 2178 (1899).

    Google Scholar 

  4. German Patent No. 70,862 (1892); Friedl., 3, 34 (1894).

  5. Heterocyclic Compounds [Russian translation], Vol. 5, Inostr. Lit., Moscow (1961), p. 218.

  6. K. J. Morgan and A. M. Turner, Tetrahedron, 25, 915 (1969).

    Google Scholar 

  7. V. Sterba, J. Arient, and J. Slosar, Coll. Czech. Chem. Commun., 31, 1093 (1966).

    Google Scholar 

  8. K. J. Morgan, J. Chem. Soc., 2343 (1961).

  9. Yu. N. Sheinker, A. M. Simonov, Yu. M. Yutilov, V. N. Sheinker, and E. I. Perel'shtein, Zh. Organ. Khim., 2, 917 (1966).

    Google Scholar 

  10. J. Pimentel and A. McClellan, The Hydrogen Bond, W. H. Freeman (1960).

  11. L. K. Dyall, Spectrochim. Acta, 25A, 1727 (1969).

    Google Scholar 

  12. L. K. Dyall and J. S. Kemp, Spectrochim. Acta, 22, 467 (1966).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 115–116, January, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shchel'tsyn, V.K., Kaminskii, A.Y., Shapirovskaya, T.P. et al. Synthesis and IR spectra of 2-phenylbenzimidazole and its amino derivatives. Chem Heterocycl Compd 9, 103–104 (1973). https://doi.org/10.1007/BF00476163

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00476163

Keywords

Navigation