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Chemistry of Heterocyclic Compounds

, Volume 9, Issue 1, pp 63–65 | Cite as

Correlation between the mass-spectrometric behavior and chromatographic mobility of epimeric 4-alkyl-1,2-dimethyl-trans-perhydroquinolol N-oxides

  • N. S. Vul'fson
  • V. G. Zaikin
  • A. A. Bakaev
  • A. A. Akhrem
  • L. I. Ukhova
  • N. F. Marchenko
Article
  • 22 Downloads

Abstract

The dependence between the Chromatographic mobility, the character of the disintegration under electron impact, and the configuration at C(4) was found for epimeric N-oxides of 1,2-dimethyl-4-ethyl-,-4-vinyl-, and -4-ethynylperhydro-4-quinolols. It Is proposed that this dependence be used to determine the configuration at C(4) in 1,4-dialkyl-trans-perhydro-4-quinolols, from which two epimeric N-oxides can be obtained.

Keywords

Organic Chemistry Vinyl Electron Impact Chromatographic Mobility 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    V. G. Zaikin, N. S. Vul'fson (Wulfson), V. I. Zaretskii, A. A. Bakaev, A. A. Akhrem, L. I. Ukhova, and N. F. Uskova, Organic Mass Spectrometry, 2, 1257 (1969).Google Scholar
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    N. S. Vul'fson, A. A. Bakaev, V. G. Zaikin, A. A. Akhrem, L. I. Ukhova, and N. F. Marchenko, Izv. Akad. Nauk SSSR, Ser. Khim., 215 (1972).Google Scholar
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    A. A. Akhrem, L. I. Ukhova, and N. F. Sakovich, Izv. Akad. Nauk SSSR, Ser. Khim., 838 (1963).Google Scholar
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Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1975

Authors and Affiliations

  • N. S. Vul'fson
    • 1
    • 2
    • 3
  • V. G. Zaikin
    • 1
    • 2
    • 3
  • A. A. Bakaev
    • 1
    • 2
    • 3
  • A. A. Akhrem
    • 1
    • 2
    • 3
  • L. I. Ukhova
    • 1
    • 2
    • 3
  • N. F. Marchenko
    • 1
    • 2
    • 3
  1. 1.M. M. Shemyakin Insitute of the Chemistry of Natural CompoundsAcademy of Sciences of the USSRMoscow
  2. 2.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow
  3. 3.Institute of Physical Organic ChemistryAcademy of Sciences of the Belorussian SSRMinsk

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