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Investigations in the field of vinyl esters of the furan series

XI. Investigation of the kinetics of the alkaline hydrolysis of vinyl esters of acids of the furan series by a polarographic method

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The kinetics of the alkaline hydrolysis of vinyl esters of furan-2-carboxylic, trans-β-(2-furyl)acrylic, and trans-cinnamic acids and also the comparative electrochemical activities of these compounds and of vinyl esters of 5-bromofuran-2-carboxylic, 5-nitro-furan-2-carboxylic, and benzoic acids have been studied by a polarographic method. A symbatic increase in the rate of hydrolysis of the esters with a shift of the potential of the half-wave of reduction into the more negative region has been established. Both the polarity and the polarizability of the molecules have a fundamental influence on the properties of the esters.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    G. G. Skvortsova, Yu. A. Mansurov & N. M. Deriglazov

Authors
  1. G. G. Skvortsova
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  2. Yu. A. Mansurov
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  3. N. M. Deriglazov
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Additional information

For Communication X, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 33–36, January, 1974.

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Skvortsova, G.G., Mansurov, Y.A. & Deriglazov, N.M. Investigations in the field of vinyl esters of the furan series. Chem Heterocycl Compd 10, 27–29 (1974). https://doi.org/10.1007/BF00475901

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  • DOI: https://doi.org/10.1007/BF00475901

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