Abstract
A comparison of the IR and UV spectra of 2-alkyl(aralkyl)amino-4H-1,3-thiazines with the spectra of model compounds showed that the amino form of the aminothiazines predominates. The basicities of the synthesized compounds were determined, and the structure of the cation formed on protonation is discussed.
Similar content being viewed by others
Literature cited
B. V. Unkovskii, L. A. Ignatova, P. L. Ovechkin, and A. I. Vinogradova, Khim. Geterotsikl. Soedin., 1690 (1970).
R. Sayre, J. Am. Chem. Soc., 77, 6689 (1955).
A. Comrie, J. Chem. Soc., 3478 (1964).
Yu. N. Sheinker, Yu. M. Yutilov, A. M. Simonov, V. N. Sheinker, and E. I. Perel'shtein, Zh. Organ. Khim., 2, 917 (1966).
K. Nagarajan and V. Rao, Ind. J. Chem., 7, 964 (1969).
W. Anderson and R. Silverstein, Anal. Chem., 37, 1417 (1965).
M. I. Kabachnik, V. A. Gilyarov, B. A. Korolev, and T. A. Raevskaya, Izv. AN SSSR, Otd. Khim. Nauk, 772 (1970).
A. Albert and E. Serjeant, Ionization Constants of Acids and Bases, Methuen (1962).
R. Mathes, F. Steward, and F. Swedish, J. Am. Chem. Soc., 70, 1452 (1948).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii. No. 7, pp. 946–949, July, 1971.
Rights and permissions
About this article
Cite this article
Ovechkin, P.L., Ignatova, L.A. & Unkovskii, B.V. Structures and tautomerism of substituted 2-amino-4H-1.3-thiazines. Chem Heterocycl Compd 7, 882–885 (1971). https://doi.org/10.1007/BF00475716
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00475716