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Chemistry of Heterocyclic Compounds

, Volume 7, Issue 7, pp 859–862 | Cite as

Alkynyl derivatives of selenophene

I. Synthesis and some transformations of selenienyl alkynyl alcohols and ketones
  • A. S. Nakhmanovich
  • V. N. Elokhina
  • R. V. Karnaukhova
Article

Abstract

The reaction of alkylacetylenes and acetylenes with 2-formylselenophene and its derivatives has given the previously unknown selenienyl alkynyl alcohols, which are oxidized to the corresponding ketones by MnO2. The reactions of the latter with hydrazine and hydroxylamine were investigated, as a result of which selenienyl-substituted pyrazoles and isoxazoles were obtained.

Keywords

Alcohol Organic Chemistry Ketone Acetylene Hydrazine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    F. Bohlman, K. Kleine, and H. Bornowski, Chem. Ber., 95, 2934 (1962).Google Scholar
  2. 2.
    A. Veitickunas, R. Miller, and F. F. Nord, J. Qrg. Chem., 16, 199, 1603 (1951).Google Scholar
  3. 3.
    M. F. Shostakovskii, A. S. Nakhmanovich, V. I. Knutov, and L. G. Klochkova, Izv. Sibirsk. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 5, 104 (1968).Google Scholar
  4. 4.
    É. N. Deryagina, A. S. Nakhmanovich, and V. N. Elokhina, USSR Author's Certificate No. 251,588 (1968); Byull. Izobr., No. 28 (1969).Google Scholar
  5. 5.
    L. I. Vereshchagin, S. P. Korshunov, R. I. Katkevich, and T. V. Lipovich, Zh. Organ. Khim., 3, 982, 1076 (1967).Google Scholar
  6. 6.
    I. A. Favorskaya and M. M. Plekhotkina, Zh. Organ. Khim., 3, 1965 (1967).Google Scholar
  7. 7.
    S. V. Tsukerman, V. D. Orlov, Yu. S. Rozum, and V. F. Lavrushin, Khim. Geterotsikl. Soedin., 4, 623 (1969).Google Scholar

Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1974

Authors and Affiliations

  • A. S. Nakhmanovich
    • 1
  • V. N. Elokhina
    • 1
  • R. V. Karnaukhova
    • 1
  1. 1.Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRIrkutsk

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