Abstract
The previously unknown 1-methyl-2-chloromethylperimidine was synthesized. The chlorine atom in it has high lability and is readily exchanged under the influence of S, O, N, and C nucleophiles. It is shown that 1-methyl-2-cyanomethylperimidine exists in the methylidene form.
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V. V. Dal'nikovskaya, T. A. Kuz'menko, and A. F. Pozharskii, Khim. Geterotsikl. Soedin., No. 10, 1389 (1986).
A. F. Pozharskii and V. V. Dal'nikovskaya, Usp. Khim., 50, 1559 (1981).
F. Sachs, Liebigs Ann., 365, 53 (1909).
V. Paragamian, M. B. Baker, B. M. Puma, and J. Reale, J. Heterocycl. Chem., 5, 591 (1968).
V. V. Kuz'menko and A. F. Pozharskii, Khim. Geterotsikl. Soedin., No. 7, 977 (1978).
E. R. Zakhs, M. A. Subbotina, and V. A. El'tsov, Zh. Org. Khim., 15, 200 (1979).
G. Ciurdary and V. I. Denes, Rev. Roumaine Chim., 14, 1063 (1969).
G. Hansen and J. Dehnert, French Patent No. 1361778; Chem. Abstr., 61, 14682 (1964).
A. F. Pozharskii, I. S. Kashparov, Yu. P. Andreichikov, A. I. Buryak, A. A. Konstantinchenko, and A. M. Simonov, Khim. Geterotsikl. Soedin., No. 6, 807 (1971).
O. Christmann, Chem. Ber., 98, 1282 (1965).
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See [1] for Communication 59.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 827–830, Junek 1988.
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Pozharskii, A.F., Tsarevskaya, E.V. & Rudnev, M.I. Heterocyclic analogs of pleiadiene 60. Synthesis and properties of 1-methyl-2-chloromethylperimidine. Chem Heterocycl Compd 24, 678–681 (1988). https://doi.org/10.1007/BF00475607
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DOI: https://doi.org/10.1007/BF00475607