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Pyrimidines

XXXIV. Synthesis and some properties of pyrimidine-2-aldoximes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Pyrimidine-2-aldoxime and 4,6-dimethylpyrimidine-2-aldoxime were obtained by oximation of the corresponding aldehydes. On the basis of spectral data, it was shown that the oximes have the syn configuration. syn-4, 6-Dimethylpyrimidine-2-aldoxtme is converted to the corresponding anti isomer by photochemical isomerization. 1-Methyl-2-oximidomethylpyrimidinium iodide was obtained by the action of methyl iodide on pyrimidine-2-aldoxime.

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See [1] for the preceding communication.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1422–1424, October, 1972.

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Gracheva, É.A., Mamaev, V.P. Pyrimidines. Chem Heterocycl Compd 8, 1284–1286 (1972). https://doi.org/10.1007/BF00475549

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  • DOI: https://doi.org/10.1007/BF00475549

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