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Heteroorganic furan derivatives. 62. The molecular and crystal structure and reactivity of 2-furylhydrosilanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

In contrast to reported hydrosilanes with alkyl and aromatic substituents at the silicon atom, 2-furyl-, di(2-furyl)- and tri(2-furyl)silanes undergo dehydrocondensation with water, while di(2-furyl)silane also undergoes this reaction with ethanol in the absence of catalyst. The structures of 2-furyl-, di(2-furyl)- and tri(2-furyl)silane were studied by electron diffraction.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    N. P. Erchak, R. N. Ziatdinova, O. A. Litvinov, V. A. Naumov & é. Lukevits

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, 420083, Kazan

    N. P. Erchak, R. N. Ziatdinova, O. A. Litvinov, V. A. Naumov & é. Lukevits

Authors
  1. N. P. Erchak
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  2. R. N. Ziatdinova
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  3. O. A. Litvinov
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  4. V. A. Naumov
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  5. é. Lukevits
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Additional information

For Communication 61, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 25–30, January, 1987.

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Erchak, N.P., Ziatdinova, R.N., Litvinov, O.A. et al. Heteroorganic furan derivatives. 62. The molecular and crystal structure and reactivity of 2-furylhydrosilanes. Chem Heterocycl Compd 23, 18–23 (1987). https://doi.org/10.1007/BF00475466

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  • DOI: https://doi.org/10.1007/BF00475466

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