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Heteroorganic furan derivatives. 61. Trimethyl(5-methyl-2-furyl)silane and trimethyl(5-methyl-2-furyl)germane

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The transformations of trimethyl(5-methyl-2-furyl)silane and trimethyl(5-methyl-2-furyl)germane were studied upon vapor-phase oxidation by atmospheric oxygen on a V-Mo-Ag-O catalyst. Under these conditions, trimethyl(5-formyl-2-furyl)-silane and trimethyl(5-formyl-2-furyl)germane are formed albeit in only 5–7% yield. This low yield is a consequence of the thermal instability of the starting compounds and the aldehydes formed. The oxidation of 2-methyl-5-tert-butylfuran was studied under comparable conditions. The corresponding aldehyde was obtained in 30% yield. A scheme was proposed for the catalytic oxidation of 5-substituted 2-methylfurans.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    é. Lukevits, L. M. Ignatovich, I. G. Iovel', Yu. Sh. Gol'dberg & M. V. Shimanskaya

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  1. é. Lukevits
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  2. L. M. Ignatovich
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  3. I. G. Iovel'
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  4. Yu. Sh. Gol'dberg
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  5. M. V. Shimanskaya
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Additional information

For Communication 60, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 22–24, January, 1987.

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Lukevits, é., Ignatovich, L.M., Iovel', I.G. et al. Heteroorganic furan derivatives. 61. Trimethyl(5-methyl-2-furyl)silane and trimethyl(5-methyl-2-furyl)germane. Chem Heterocycl Compd 23, 15–17 (1987). https://doi.org/10.1007/BF00475465

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  • DOI: https://doi.org/10.1007/BF00475465

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