Abstract
The reaction of 2-aminopyridines with PCl5 proceeds with the formation of 2-trichlorophosphazopyridines, which when treated with morpholine are converted to 2-dimorpholidochlorophosphazopyridines. By heating these last products with 96% ethanol, dimorpholido pyridyl-2-amidophosphoric acids are obtained.
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References
A. A. Kropacheva and N. V. Sazonov, KhGS, collection 1, 372, 1967.
N. V. Sazonov and A. A. Kropacheva, KhGS, collection 1, 377, 1967.
G. I. Derkach, I. N. Zhmurova, A. V. Kirsanov, V. I. Shevchenko, and A. S. Shtepanek, Phosphazo Compounds [in Russian], Naukova dumka, Kiev, 1965.
O. E. Polansky and M. A. Grassberger, Mon., 94, 662, 1963.
A. Katritzky and J. Lagovskaya, Chemistry of Heterocyclic Compounds, [Russian translation], IL, Moscow, 73, 1963.
G. I. Derkach, M. I. Bukovskii, S. N. Solodushnikov, and A. M. Mosiichuk, in collection “Chemistry of Organophosphorus Compounds”, ZhOKh, 89, 1967.
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Sazonov, N.V., Kropacheva, A.A. Reactions of 2-aminopyridines with phosphorus pentachloride. Chem Heterocycl Compd 6, 51–53 (1970). https://doi.org/10.1007/BF00475423
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DOI: https://doi.org/10.1007/BF00475423