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Dipole moments, molar kerr constants, and three-dimensional structure of some 4,5-dihydro-1, 3,5-dithiazines

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Abstract

The three-dimensional structure of some 4,5-dihydro-1,3,5-dithiazine derivatives was investigated by means of dipole moments and the Kerr effect. The presence of equilibrium boat and chair forms in the conformational mixture is proposed for the 2,4,6-trimethyl and 2,4,-5, 6-tetramethyl derivatives. Energy data that confirm the possibility of anomalous conformations are presented.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, V. I. Ul'yanov-Lenin Kazan State University, Kazan

    G. G. Butenko, A. N. Vereshchagin & B. A. Arbuzov

Authors
  1. G. G. Butenko
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  2. A. N. Vereshchagin
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  3. B. A. Arbuzov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 321–324, March, 1972.

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Butenko, G.G., Vereshchagin, A.N. & Arbuzov, B.A. Dipole moments, molar kerr constants, and three-dimensional structure of some 4,5-dihydro-1, 3,5-dithiazines. Chem Heterocycl Compd 8, 290–293 (1972). https://doi.org/10.1007/BF00475283

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  • DOI: https://doi.org/10.1007/BF00475283

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