Abstract
A new procedure for preparing 2-methyl-6-methoxy-4-thioquinolone (I), 2-methyl-7-chloro-4-thioquinoline (II), 2-thiopyridone (III) and 5-nitro-2-thiopyridone (IV) has been proposed. This involves the reactions of the corresponding halogen derivatives of quinoline and pyridine with sodium thiosulfate. Compounds I and II were synthesized for the first time.
Similar content being viewed by others
References
A. V. Voropaeva and N. G. Garbar, KhGS [Chemistry of Heterocyclic Compounds], 677, 1969.
I. Renault and M. M. Delepine, C. r., 232, 77, 1951.
A. Binz and C. RÄth, Ann., 487, 105, 1931.
M. A. Phillips and H. Sapiro, J. Chem. Soc., 584, 1942.
R. I. Thirtle, J. Am. Chem. Soc., 68, 342, 1946.
T. Takahashi, K. Ueda, and J. Iwai, Vakugaku Zassni, 78, 1447, 1958; C. A., 53, 8133a, 1959.
B. Sorbo, Acta Chem. Scand., 12, 1358, 1958.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Voropaeva, A.V., Garbar', N.G. Syntheses in the pyridine series. Chem Heterocycl Compd 6, 168–169 (1970). https://doi.org/10.1007/BF00474989
Issue Date:
DOI: https://doi.org/10.1007/BF00474989