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Synthesis and some reactions of sulfides of the thiophene series

XIV. The action of bromine and n-bromosuccinimide on some chelates of mercaptoaldimines of the thiophene series

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The bromination of metal complexes of mercaptothenylide neimines of types I and II with bromine and N-bromosuccinimide leads to the cleavage of the chelate ring and the formation of the corresponding thieno [3, 2-d]-and thieno [2, 3-d]isothiazolium bromides (IIIa, b).

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References

  1. J. P. Collman, Angew. Chem., 77, 154, 1965.

    Google Scholar 

  2. E. Bayer, Angew. Chem., 73, 533, 1961.

    Google Scholar 

  3. N. K. Chawla and M. M. Jones, Inorg. Chem. 3, 1549, 1964.

    Google Scholar 

  4. K. D. Maguire and M. M. Jones, J, Am. Chem. Soc, 85, 154, 1963; 84, 2316, 1962.

    Google Scholar 

  5. Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, ser. khim., 897, 1966.

  6. Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, KhGS [Chemistry of Heterocyclic Compounds], 71, 1967.

  7. R. W. Kluiber, J. Am. Chem. Soc, 82, 4839, 1960.

    Google Scholar 

  8. J. P. Collman, R. A. Moss, H. Maltz, and C. C. Heindel, J. Am. Chem. Soc, 83, 531, 1961.

    Google Scholar 

  9. R. W. Kluiber, U. S. Patent 3014939, 1961; RZhKh, 1963, 15N60.

  10. Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, KhGS [Chemistry of Heterocyclic Compounds], 1, 220, 1965.

    Google Scholar 

  11. R. Layer, Chem. Rev., 63, 501, 1963.

    Google Scholar 

  12. J. W. Mellor, A Comprehensive Treatise on Inorganic and Theoretical Chemistry, London, New York, 4, 571, 1929.

    Google Scholar 

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Gol'dfarb, Y.L., Kalik, M.A. Synthesis and some reactions of sulfides of the thiophene series. Chem Heterocycl Compd 3, 799–803 (1967). https://doi.org/10.1007/BF00474872

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  • DOI: https://doi.org/10.1007/BF00474872

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