Abstract
The bromination of metal complexes of mercaptothenylide neimines of types I and II with bromine and N-bromosuccinimide leads to the cleavage of the chelate ring and the formation of the corresponding thieno [3, 2-d]-and thieno [2, 3-d]isothiazolium bromides (IIIa, b).
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J. P. Collman, Angew. Chem., 77, 154, 1965.
E. Bayer, Angew. Chem., 73, 533, 1961.
N. K. Chawla and M. M. Jones, Inorg. Chem. 3, 1549, 1964.
K. D. Maguire and M. M. Jones, J, Am. Chem. Soc, 85, 154, 1963; 84, 2316, 1962.
Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, ser. khim., 897, 1966.
Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, KhGS [Chemistry of Heterocyclic Compounds], 71, 1967.
R. W. Kluiber, J. Am. Chem. Soc, 82, 4839, 1960.
J. P. Collman, R. A. Moss, H. Maltz, and C. C. Heindel, J. Am. Chem. Soc, 83, 531, 1961.
R. W. Kluiber, U. S. Patent 3014939, 1961; RZhKh, 1963, 15N60.
Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, KhGS [Chemistry of Heterocyclic Compounds], 1, 220, 1965.
R. Layer, Chem. Rev., 63, 501, 1963.
J. W. Mellor, A Comprehensive Treatise on Inorganic and Theoretical Chemistry, London, New York, 4, 571, 1929.
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Gol'dfarb, Y.L., Kalik, M.A. Synthesis and some reactions of sulfides of the thiophene series. Chem Heterocycl Compd 3, 799–803 (1967). https://doi.org/10.1007/BF00474872
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DOI: https://doi.org/10.1007/BF00474872