Abstract
2-Formyl-5-nitrothiophene has high reactivity with respect to phosphoranes, with which it reacts quantitatively to give l-aryl-3-(5-nitro-2-thienyl)propenones. The reaction can be used for the qualitative detection of phosphoranes.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
K. K. Venter, S. A. Giller, V. F. Kucherov, V. V. Tsirule, and A. M. Karklinya, Dokl. Akad. Nauk SSSR, 31, 1073 (1961).
A. Johnson, Chemistry of Ylids [Russian translation], Mir, Moscow (1969).
S. V. Tsukerman, V. M. Nikitchenko, and V. F. Lavrushin, Zh. Obshch. Khim., 32, 2324 (1962).
K. Nakanishi, Infrared Spectroscopy, Practical, Holden-Day, San Francisco (1962).
L. Bellamy, New Data on the IR Spectra of Complex Molecules [Russian translation], Mir, Moscow (1971).
R. Mecke and K. Noack, Chem. Ber., 93, 210 (1960).
K. Noack and R. N. Jones, Canad. J. Chem., 39, 2201 (1961).
R. L. Erskine and E. S. Waight, J. Chem. Soc., 3425 (1960).
F. N. Cottee, B. P. Straugham, C. J. Timmons, W. F. Forbes, and R. Shilton, J. Chem. Soc., B, 1146 (1967).
S. V. Tsukerman, V. M. Nikitchenko, Yu. S. Rozum, and V. F. Lavrushin, Khim. Geterotsikl. Soedin., 452 (1967).
V. D. Orlov, S. V. Tsukerman, and V. F. Lavrushin, Problems of Stereochemistry, Mezhved. Resp. Sb. (1971), No. 1, p. 89.
V. I. Savin and Yu. P. Kitaev, Zh. Organ. Khim., 9, 1101 (1973).
Ya. A. éidus, K. K. Venter, and I. V. Zuika, Khim. Geterotsikl. Soedin., 402 (1967).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1624–1625, December, 1974.
Rights and permissions
About this article
Cite this article
Listvan, V.N. 2-Formyl-5-nitrothiophene as a reagent for phosphoranes. Chem Heterocycl Compd 10, 1427–1428 (1974). https://doi.org/10.1007/BF00474321
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00474321