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Mass spectrometry of macroheterocycles. 1. Mass spectra of isomeric bicyclic crown ethers

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The fundamental, fragmentation paths under electron impact of bridged crown ethers and the condensed, bicyclic crown ethers isomeric to them have been established by means of a combination of techniques (DADI, metastable defocusing, high resolution). The mass spectral criteria of the compounds in the series considered have been determined, as well as the characteristic ion peaks, the intensity of which permit the isomeric compounds to be distinguished.

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Authors and Affiliations

  1. A. V. Bogatskii Physical Chemical Institute, Academy of Sciences of the Ukrainian SSR, Odessa

    A. I. Gren', A. V. Mazepa, A. V. Lobach, N. G. Luk'yanenko & O. S. Timofeev

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  1. A. I. Gren'
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  2. A. V. Mazepa
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  3. A. V. Lobach
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  4. N. G. Luk'yanenko
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  5. O. S. Timofeev
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 323–326, March, 1991.

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Gren', A.I., Mazepa, A.V., Lobach, A.V. et al. Mass spectrometry of macroheterocycles. 1. Mass spectra of isomeric bicyclic crown ethers. Chem Heterocycl Compd 27, 262–265 (1991). https://doi.org/10.1007/BF00474225

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  • DOI: https://doi.org/10.1007/BF00474225

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