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Benzindoles. 18. Some electrophilic substitution reactions involving the hydrogen atoms in 4,5,6,7-dibenzindole

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Abstract

The principal electrophilic substitution reactions involving the hydrogen atom of 4,5,6,7-dibenzindole — the Vilsmeier reaction, the Mannich reaction, diazo coupling, and acylation — were studied, and a qualitative comparison of its reactivities with indole and 4,5- and 6,7-benzindoles was made. It was established that 4,5,6,7-dibenzindole has the most clearly expressed electron-donor properties. The structures of the synthesized compounds were proved by data from the IR, UV, PMR, and mass spectra.

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Authors and Affiliations

  1. D. I. Mendeleev Moscow Institute of Chemical Technology, 125047, Moscow

    R. M. Mirzametova, V. N. Buyanov & N. N. Suvorov

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  1. R. M. Mirzametova
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  2. V. N. Buyanov
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  3. N. N. Suvorov
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Additional information

See [1] for communication 17.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 366–370, March, 1979.

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Mirzametova, R.M., Buyanov, V.N. & Suvorov, N.N. Benzindoles. 18. Some electrophilic substitution reactions involving the hydrogen atoms in 4,5,6,7-dibenzindole. Chem Heterocycl Compd 15, 302–306 (1979). https://doi.org/10.1007/BF00474097

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  • DOI: https://doi.org/10.1007/BF00474097

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