Abstract
In the reaction of the cis-syn-cis and cis-anti-cis diastereomers of dicyclohexano-18-crown-6 with 2-nitro and 2,4-dinitroaniline crystalline complexes with a 1:2 stoichiometric composition were obtained only when the cis-anti-cis diastereomer was used. The three-dimensional structure of the complex of the cis-anti-cis diastereomer of dicyclohexano-18-crown-6 with 2,4-dinitroaniline was determined by an x-ray diffraction study. The complexing of o-nitroanilines with the cis-anti-cis diastereomer is explained by the topological conformity of the interacting compounds. The isolation of the individual cis diastereomers from the mixture of them formed as a result of the catalytic hydrogenation of dibenzo-18-crown-6 was accomplished by means of the selective formation of the crystalline complex of the cis-anti-cis diastereomer with 2-nitroaniline.
Similar content being viewed by others
Literature Cited
F. Vögtle, Zh. Vses. Khim. Obshch. im. D. I. Mendeleeva, 36, 500 (1985).
F. Vögtle, H. Sieger, and W. M. Müller, Host-Guest Complex Chemistry, Vol. 1, edited by F. Vögtle, Berlin (1981), p. 107.
A. Elbasyouny, H. J. Brügge, K. Deuten, M. Dickel, A. Knöchel, K. U. Koch, J. Kopf, D. Melzer, and G. Rudolph, J. Am. Chem. Soc., 105, 6568 (1983).
G. Weber and G. M. Sheldrick, Acta Cryst., B37, 2108 (1981).
Yu. G. Ganin, Yu. A. Simonov, and T. I. Malinovskii, Izv. Akad. Nauk Moldavsk. SSR, Ser. Fiz.-Tekh. Mat. Nauk, No. 1, 18 (1985).
N. K. Dalley, D. E. Smith, and S. B. Larson, J. Chem. Soc., Chem. Commun., No. 1, 43 (1975).
N. F. Krasnova, Yu. A. Simonov, V. V. Yakshin, and M. B. Korshunov, Kristallografiya, 32, No. 2, 499 (1987).
J. Dale, Acta Chem. Scand., 27, 1115 (1973).
Yu. A. Simonov, N. F. Krasnova, N. A. Tsarenko, V. K. Bel'skii, V. V. Yakshin, and B. N. Laskorin, Dokl. Akad. Nauk SSSR, 285, 892 (1985).
A. Domenicano and P. Murrey-Rust, Tetrahedron Lett., No. 24, 2283 (1979).
J. R. Holden, Ch. Dichinson, and Ch. M. Boch, J. Phys. Chem., 76, 3597 (1972).
M. Hiraoka, Crown Compounds: Properties and Application [Russian translation], Mir, Moscow (1986).
P. Main, S. E. Hull, L. Lessinger, G. Germain, J.-P. Declerco, and M. M. Woolfson, MULTAN 78. A System of Computer Programs for the Automatic Solution of Crystal Structures from X-Ray Diffraction Data, University of York, England and University of Louvain, Belgium (1978).
V. K. Pechorskii, P. Yu. Zavalii, and L. G. Aksel'rud, Vestn. L'vov. Univ., No. 25, 9 (1984).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1190–1195, September, 1988.
Rights and permissions
About this article
Cite this article
Ganin, é.V., Makarov, V.F., Kotlyar, S.A. et al. Synthesis and structures of molecular complexes of the cis-anti-cis diastereomer of dicyclohexano-18-crown-6 with o-nitroanilines. Chem Heterocycl Compd 24, 979–984 (1988). https://doi.org/10.1007/BF00474040
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00474040