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Synthesis and transformations of polyhedral compounds 12. Stevens rearrangement in the azaadamantane series

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Some quaternary salts of 1,3-diaza- and 1,3,5-triazaadamantanes undergo the Stevens rearrangement to give derivatives of the corresponding 1,4-diaza- and 1,3,6-triazahomoadamantanes. The structures of the rearrangement products were proved by IR, PMR, and mass spectroscopy and x-ray diffraction analysis (XDA).

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Authors and Affiliations

  1. A. L. Mndzhoyan Institute of Fine Organic Chemistry, Academy of Sciences of the Armenian SSR, 375014, Yerevan

    G. G. Minasyan, A. A. Karapetyan, Ts. E. Agandzhanyan & Yu. T. Struchkov

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, 117813, Moscow

    G. G. Minasyan, A. A. Karapetyan, Ts. E. Agandzhanyan & Yu. T. Struchkov

Authors
  1. G. G. Minasyan
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  2. A. A. Karapetyan
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  3. Ts. E. Agandzhanyan
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  4. Yu. T. Struchkov
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Additional information

See [1] for Communication 11.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 669–673, May, 1991.

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Minasyan, G.G., Karapetyan, A.A., Agandzhanyan, T.E. et al. Synthesis and transformations of polyhedral compounds 12. Stevens rearrangement in the azaadamantane series. Chem Heterocycl Compd 27, 534–537 (1991). https://doi.org/10.1007/BF00474002

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  • DOI: https://doi.org/10.1007/BF00474002

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