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Saturated nitrogen-containing heterocycles. 15. Catalytic synthesis and isomerization of 9-substituted10-methylperhydroacridines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

In the catalytic hydromethylamination of 8-substituted 2-hydroxytricyclo[7.3.1.02,7]tridecane-13-ones they are converted into 9-substituted 10-methyl-Δ9,9a-dodecahydroacridines and 10-methylperhydroacridines with trans,anti,cis- and cis,syn,cis-conformation. The ability of the latter to isomerize into the trans,cis,tans-form has been established.

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For Communication 14, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 200–204, February, 1992.

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Nikolaeva, T.G., Yudovich, L.M., Pastukhova, A.A. et al. Saturated nitrogen-containing heterocycles. 15. Catalytic synthesis and isomerization of 9-substituted10-methylperhydroacridines. Chem Heterocycl Compd 28, 163–166 (1992). https://doi.org/10.1007/BF00473937

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  • DOI: https://doi.org/10.1007/BF00473937

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