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Ring-chain isomerism of 1,3,3-trimethyl-2-formylmethylene-indoline (fischer aldehyde) oxime and associated reactions

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The compound 1,3,3-trimethyl-2-formylmethyleneindoline oxime is synthesized for the first time. Using the polynuclear resonance method it is shown that the oxime exists as two isomers, one of which has a cyclic structure. A number of reactions are carried out involving the carbocyclic and oxime parts of the molecule.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ukrainian Academy of Sciences, Kiev

    A. A. Tolmachev, L. N. Babichenko, I. V. Komarov, S. V. Sereda & A. K. Sheinkman

  2. Dnepropetrovsk Engineering and Construction Institute, Dnepropetrovsk

    A. A. Tolmachev, L. N. Babichenko, I. V. Komarov, S. V. Sereda & A. K. Sheinkman

Authors
  1. A. A. Tolmachev
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  2. L. N. Babichenko
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  3. I. V. Komarov
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  4. S. V. Sereda
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  5. A. K. Sheinkman
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 183–189, February, 1992.

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Tolmachev, A.A., Babichenko, L.N., Komarov, I.V. et al. Ring-chain isomerism of 1,3,3-trimethyl-2-formylmethylene-indoline (fischer aldehyde) oxime and associated reactions. Chem Heterocycl Compd 28, 148–153 (1992). https://doi.org/10.1007/BF00473933

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  • DOI: https://doi.org/10.1007/BF00473933

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