Abstract
The reaction of hexamethyldisiloxane with 2-ethoxy-1,3-dioxolane is described. It is shown that cleavage of the endo- and exocyclic carbon-oxygen bonds of the ortho ester occurs under mild conditions (16–20‡C) in the presence of acidic catalysts with the formation of 2-(trimethylsiloxy)ethyl formate, the subsequent transformation of which leads to ethyl formate, trimethylethoxysilane, and 1,2-bis(trimethylsiloxy)ethane.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1607–1611, December, 1989.
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Zhurkina, I.P., Nedogrei, E.P., Musavirov, R.S. et al. Reaction of hexamethyldisiloxane with 2-ethoxy-1,3-dioxolane. Chem Heterocycl Compd 25, 1338–1342 (1989). https://doi.org/10.1007/BF00473860
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DOI: https://doi.org/10.1007/BF00473860