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Chemistry of Heterocyclic Compounds

, Volume 23, Issue 8, pp 878–880 | Cite as

Electrochemical oxidation of substituted 1H-1,2-diazaphenalenes

  • A. B. Dmitriev
  • M. S. Okolelova
  • N. N. Bogdashev
  • D. M. Elisevich
  • A. L. Kazakov
Article

Abstract

It was shown by cyclic voltammetry and electrolysis at controlled potential at a platinum electrode and also by TLC and UV spectroscopy that the electrochemical oxidation of substituted 1H-1,2-diazaphenalenes in anhydrous acetonitrile takes place in a single one-electron stage with the formation of a stable radicalation. The oxidation potentials of a series of derivatives of 1H-1,2-diazaphenalene and the parameters of the equation for the correlation of these potentials with the Taft substituent constants were determined.

Keywords

Oxidation Spectroscopy Platinum Organic Chemistry Acetonitrile 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • A. B. Dmitriev
    • 1
  • M. S. Okolelova
    • 1
  • N. N. Bogdashev
    • 1
  • D. M. Elisevich
    • 1
  • A. L. Kazakov
    • 1
  1. 1.Pyatigorsk Pharmaceutical InstituteUSSR

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