Abstract
It was shown by cyclic voltammetry and electrolysis at controlled potential at a platinum electrode and also by TLC and UV spectroscopy that the electrochemical oxidation of substituted 1H-1,2-diazaphenalenes in anhydrous acetonitrile takes place in a single one-electron stage with the formation of a stable radicalation. The oxidation potentials of a series of derivatives of 1H-1,2-diazaphenalene and the parameters of the equation for the correlation of these potentials with the Taft substituent constants were determined.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1098–1100, August, 1987.
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Dmitriev, A.B., Okolelova, M.S., Bogdashev, N.N. et al. Electrochemical oxidation of substituted 1H-1,2-diazaphenalenes. Chem Heterocycl Compd 23, 878–880 (1987). https://doi.org/10.1007/BF00473465
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DOI: https://doi.org/10.1007/BF00473465