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Chemistry of Heterocyclic Compounds

, Volume 23, Issue 8, pp 871–874 | Cite as

Reduction of enamines of the 3,3-dialkyl-3,4-dihydroisoquinoline series

  • M. S. Gavrilov
  • V. S. Shklyaev
  • B. B. Aleksandrov
Article

Abstract

Lithium aluminum hydride reduced enamines of the 3,3-dialkyl-3,4-dihydroisoquinoline series to the corresponding tetrahydroisoquinolines. In the presence of a hydrogen atom at the Β-carbon atom of the enamino ester the action of lithium aluminum hydride and alkylmagnesium bromide leads to the products from the condensation of two molecules of the initial compound.

Keywords

Hydrogen Aluminum Ester Lithium Bromide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature Cited

  1. 1.
    Ya. F. Freimanis, Chemistry of Enamino Ketones, Enamino Imines, and Enamino Thiones [in Russian], Zinatne, Riga (1974), p. 275.Google Scholar
  2. 2.
    S. G. Agbalyan, L. A. Nersesyan, and A. O. Nshanyan, Izv. Akad. Nauk ArmSSR, Khim. Nauki, 1965, No. 1, 83.Google Scholar
  3. 3.
    V. S. Shklyaev, B. B. Aleksandrov, G. I. Legotkina, M. I. Vakhrin, M. S. Gavrilov, and A. G. Mikhailovskii, Khim. Geterotsikl. Soedin., 1983, No. 11, 1560.Google Scholar
  4. 4.
    M. S. Gavrilov, V. S. Shklyaev, B. B. Aleksandrov, V. V. Larikov, and A. é. Poplevin, Manuscript Deposited at VINITI, Riga (1985), No. 4180–85 dep.Google Scholar
  5. 5.
    H. Budzikiewicz, C. Djerassi, and D. H. Williams, Interpretation of Mass Spectra in Organic Compounds, Holden-Day, San Francisco (1964).Google Scholar
  6. 6.
    Organic Chemistry [Russian translation], Vol. 2, Mir, Moscow (1979), p. 198.Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • M. S. Gavrilov
    • 1
  • V. S. Shklyaev
    • 1
  • B. B. Aleksandrov
    • 1
  1. 1.Institute of Organic ChemistryPerm'

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