Abstract
An x-ray crystallographic investigation of 7,7-dimethyl-2,3-di(4-methoxyphenyl)-5-oxo-5,6,7,8-tetrahydroquinoline, obtained by the hydrolysis of its oxime, was undertaken. The oxime, together with the isomeric oxime of 7,7-dimethyl-2,4-di(4-methoxyphenyl)-5-oxo-5,6,7,8-tetrahydroquinoline, is formed in the reaction of 5,5-dimethyl-2-[1,3-di(4-methoxyphenyl)-3-oxopropyl]cyclohexane-1,3-dione with hydroxylamine hydrochloride.
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Literature Cited
B. M. Mikhailov, Zh. Obshch. Khim., 7, 2950 (1937).
V. G. Kharchenko, L. I. Markova, T. D. Kazarinova, and L. M. Yudovich, Khim. Geterotsikl. Soedin., 1985, No. 6, 846.
L. E. Sutton, Tables of Interatomic Distances and Configurations in Molecules and Ions, Special Publication No. 18, Chemical Society, London (1965).
R. F. Bryan, J. Chem. Soc., 1967, No. 12, 1311.
R. Bucourt, in: Topics in Stereochemistry, Vol. 8, Interscience, New York (1974), p. 159.
M. Cygler, K. Dobrynin, and A. Stepien, Cryst. Struct. Commun., 10, 395 (1981).
D. Mooz and H. G. Wasson, J. Chem. Phys., 75, 1517 (1981).
R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov, Kristallografiya, 28, 1029 (1983).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1085–1088, August, 1987.
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Kharchenko, V.G., Markova, L.I., Struchkov, Y.T. et al. Crystal and molecular structure of 7,7-dimethyl-2,3-di(4-methoxyphenyl)-5-oxo-5,6,7,8-tetrahydroquinoline. Chem Heterocycl Compd 23, 867–871 (1987). https://doi.org/10.1007/BF00473461
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DOI: https://doi.org/10.1007/BF00473461