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Properties of furoxans monosubstituted with adamantanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Furoxans monosubstituted with a series of adamantanes have been obtained by oxidation of anti-[1-(3-R-adamantyl)]-amphi-glyoximes. Depending on the conditions 4-(1-adamantyl)furoxan is partially isomerized to 3-(1-adamantyl)furoxan or by increasing the time of boiling and concentration of furoxan in p-xylene is isomerized to the thermodynamically stable 3-(1-adamantyl)-1,2,4-oxadiazol-5-one.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 258–261, February, 1988.

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Kalinina, M.I., Moiseev, I.K. Properties of furoxans monosubstituted with adamantanes. Chem Heterocycl Compd 24, 217–220 (1988). https://doi.org/10.1007/BF00473336

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  • DOI: https://doi.org/10.1007/BF00473336

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