Abstract
A method is proposed for the stabilization of polyheteroatomic rings consisting only of nitrogen or phosphorus atoms by introduction of acceptors of the unshared electron pair of the heteroatom, particularly oxygen atoms, with the formation of oxide forms. The positions of introduction of the acceptor groups into four- and six-membered rings were determined. The conclusions drawn were confirmed by calculations by the MNDO method of tetrazete 1,3-dioxide and 1,3-ylid and hexaphosphorine 1,3,5-trioxide and 1,3,5-ylid.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 250–255, February, 1988.
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Glukhovtsev, M.N., Simkin, B.Y. & Minkin, V.I. Stabilization of polyheteroatomic aza and phospha analogs of cyclobutadiene and benzene. Chem Heterocycl Compd 24, 210–215 (1988). https://doi.org/10.1007/BF00473334
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DOI: https://doi.org/10.1007/BF00473334