Abstract
The chlorination of 1,5-dimethylpyrazole by gaseous chlorine in acetic acid in the presence of sodium acetate affords 1-methyl-3,4-dichloro-5-(dichloromethyl)pyrazole, which is subsequently converted to the 5-(trichloromethyl) derivative.
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Literature Cited
B. I. Stepanov, V. P. Perevalov, M. A. Andreeva, and A. K. Kh. Karim, Zh. Obshch. Khim., 50, 2106 (1980).
V. P. Perevalov, M. A. Andreeva, M. I. Bolotov, and B. I. Stepanov, Khim. Geterotsikl. Soedin., No. 7, 993 (1983).
A. Gordon and R. Ford, Chemist's Companion [Russian translation], Mir, Moscow (1976).
Yu. A. Naumov and I. I. Grandberg, Usp. Khim., 35, 21 (1966).
V. P. Perevalov, A. K. Karim, A. V. Khrapov, L. I. Baryshnenkova, and B. I. Stepanov, Khim. Geterotsikl. Soedin., No. 1, 40 (1988).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 352–354, March, 1990.
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Perevalov, V.P., Manaev, Y.A., Bezborodov, B.V. et al. Chlorination of 1,5-dimethylpyrazole. Chem Heterocycl Compd 26, 301–303 (1990). https://doi.org/10.1007/BF00472550
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DOI: https://doi.org/10.1007/BF00472550