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Chemistry of Heterocyclic Compounds

, Volume 27, Issue 6, pp 607–613 | Cite as

New method for studying the reactivities of α-diazo imines. Investigation of the cyclization of N-substituted 2-diazoacetamidines to 1,2,3-triazoles

  • E. F. Dankova
  • V. A. Bakulev
  • D. P. Krut'ko
Article

Abstract

N-Substituted diazoacetamidines were generated in the reaction of N-substituted acetamidines with benzenesulfonyl azide. It is shown that their cyclization to isomeric 1,2,3-triazoles characterizes the reactivities of α-diazo imines. The synthesis of 5-amino-1,2,3-triazole derivatives was accomplished, and their 1H, 13C, and 15N NMR spectra were studied.

Keywords

Organic Chemistry Azide Triazole Triazole Derivative Benzenesulfonyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • E. F. Dankova
    • 1
  • V. A. Bakulev
    • 1
  • D. P. Krut'ko
    • 1
  1. 1.S. M. Kirov Ural Polytechnical InstituteSverdlovsk

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