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Synthesis of fluoro-substituted symmetrical dialkylaminotriazines under interphase-catalysis conditions

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of chloro derivatives of symmetrical dialkylaminotriazines with potassium fluoride in the presence of catalytic amounts of crown ethers or quaternary ammonium salts leads to the formation of the corresponding fluoro derivatives in high yields. The structure of the catalyst and the nucleophilicity of the solvent affect the yields of the fluoro derivatives of the symmetrical dialkylaminotriazines.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1370–1372, October, 1990.

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Nikolaeva, S.V., Kolbin, A.M., Sapozhnikov, Y.E. et al. Synthesis of fluoro-substituted symmetrical dialkylaminotriazines under interphase-catalysis conditions. Chem Heterocycl Compd 26, 1142–1144 (1990). https://doi.org/10.1007/BF00472187

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  • DOI: https://doi.org/10.1007/BF00472187

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