Abstract
It is shown that in the ground state of the 1-ethylideneaminoaziridine molecule there is virtually no conjugation of its unshared pair of electrons with the π electrons of the N=C bond in the case of a pyramidal structure of the inversion center. A potential surface map was constructed for the conformational transitions due to the possibility of inversion of the nitrogen atom of the heteroring and rotation about the N-N bond. The equivalence of the vicinal protons of the heteroring that is observed in the PMR spectra of the hydrazone derivatives of 1-aminoaziridine is explained.
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S. A. Giller, A. V. Eremeev, M. Yu. Lidak, V. A. Pestunovich. É. É. Liepin'sh, and I. Ya. Kalvin'sh, Khim. Geterotsikl. Soedin., No. 1, 45 (1971).
É. É. Liepin'sh, “Study of the configurations and conformations of compounds with an ethyleneimine ring by NMR spectroscopy,” Master's Dissertation, Riga (1975).
J. A. Pople and D. L. Beveridge, Approximate MO Theory, McGraw-Hill, New York (1970).
A. Rauk, J. D. Frick, R. Tang, and K. Mislow, J. Am. Chem. Soc., 93, 6507 (1971).
T. E. Turner, V. C. Fiora, and W. M. Kendrick, J. Chem. Phys., 21, 564 (1953).
J. A. Pople and M. Gordon, J. Am. Chem. Soc., 89, 4253 (1967).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 480–482, April, 1978.
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Eremeev, A.V., Shoken, M.A. Inversion of the nitrogen atom in the aziridine ring. Calculation of 1-ethylideneaminoaziridine by the CNDO/2 method. Chem Heterocycl Compd 14, 391–393 (1978). https://doi.org/10.1007/BF00472150
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DOI: https://doi.org/10.1007/BF00472150