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Competitive methylation of some phenolic compounds

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The competitive methylation of a mixture of 6-hydroxy-4-methylcoumarin and of 7-hydroxy-4-methylcoumarin and also of other compounds of phenolic nature has been studied. It had ben shown that in the presence of 1 mole of alkali, methylation of the more acidic hydroxyl takes place at the oxygen atom, and with 2 moles of alkali, the stronger conjugated base reacts.

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Literature cited

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1185–1188, September, 1974.

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Kirsanova, Z.D., Zagorevskii, V.A. & Zykov, D.A. Competitive methylation of some phenolic compounds. Chem Heterocycl Compd 10, 1029–1031 (1974). https://doi.org/10.1007/BF00472115

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  • DOI: https://doi.org/10.1007/BF00472115

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