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Establishment of the configuration of 4-benzamido-3-oxo-2-(α-hydroxyamino-δ-carbomethoxybutyl)-thiophane

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Proton magnetic resonance spectroscopy was used to establish that the addition of hydroxylamine to the exocyclic double bond of 4-benzamido-3-oxo-2-(δ-carbomethoxybutylidene)-thiophane occurs stereospecifically; the compound formed has the trans configuration with respect to the substituents in the 2 and 4 positions.

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Literature cited

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Authors and Affiliations

  1. All-Union Scientific-Research Vitamin Institute, Moscow

    S. D. Mikhno, T. M. Filippova, T. N. Polyanskaya, N. S. Kulachkina & V. M. Berezovskii

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  1. S. D. Mikhno
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  2. T. M. Filippova
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  3. T. N. Polyanskaya
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  4. N. S. Kulachkina
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  5. V. M. Berezovskii
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1600–1601, December, 1972.

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Mikhno, S.D., Filippova, T.M., Polyanskaya, T.N. et al. Establishment of the configuration of 4-benzamido-3-oxo-2-(α-hydroxyamino-δ-carbomethoxybutyl)-thiophane. Chem Heterocycl Compd 8, 1449–1450 (1972). https://doi.org/10.1007/BF00471825

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  • DOI: https://doi.org/10.1007/BF00471825

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