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Chemistry of Heterocyclic Compounds

, Volume 15, Issue 4, pp 374–377 | Cite as

Hydrogenation of difurfurylideneacetone on a raney nickel catalyst

  • R. Mat'yakubov
  • Yu. M. Mamatov
  • N. Kh. Mukhamadaliev
  • E. G. Abduganiev
Article

Abstract

1.5-Difurylpent-1-en-3-one, 1,5-difurylpentan-3-one, 1,5-ditetrahydrofurylpentan3-one, and l,5-ditetrahydrofuryl-pentan-3-ol were obtained by hydrogenation of difurfuryldieneacetone on a Raney nickel catalyst at 20–65°C and atmospheric pressure. It was established that the hydrogenation of difurfuryldieneacetone is a zero-order reaction with respect to the concentration of the starting compound. The rate constants of the reaction were found; the activation energy found for 20–65°C is 6.2±0.5 kcal/mole.

Keywords

Hydrogenation Nickel Activation Energy Organic Chemistry Nickel Catalyst 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • R. Mat'yakubov
    • 1
  • Yu. M. Mamatov
    • 1
  • N. Kh. Mukhamadaliev
    • 1
  • E. G. Abduganiev
    • 1
  1. 1.Fergana Branch, Scientific-Research Institute of PlasticsFergana

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