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2-Benzopyrylium salts. 42. Ortho-quinoid intermediates in recyclization reactions of 2-benzopyrylium salts

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The interaction of 1-styryl-substituted 2-benzopyrylium salts with morpholine, methylamine, and malononitrile is highly stereoselective informing cis-3,4-dihydronaphthalenes; this can be taken as evidence that ortho-quinoid intermediates participate in these conversions.

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Authors and Affiliations

  1. Scientific-Research Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don

    S. V. Verin, D. É. Tosunyan & E. V. Kuznetsov

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  1. S. V. Verin
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  2. D. É. Tosunyan
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  3. E. V. Kuznetsov
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Additional information

For Communication 41, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1468–1475, November, 1991.

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Verin, S.V., Tosunyan, D.É. & Kuznetsov, E.V. 2-Benzopyrylium salts. 42. Ortho-quinoid intermediates in recyclization reactions of 2-benzopyrylium salts. Chem Heterocycl Compd 27, 1183–1189 (1991). https://doi.org/10.1007/BF00471741

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  • DOI: https://doi.org/10.1007/BF00471741

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