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Reaction of pent achloropyridine with sodioacetoacetic ester

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Ethyl tetrachloro-4-pyridylacetoacetates and tetrachloro-2-pyridylacetoacetates were synthesized by reaction of pentachloropyridine with sodioacetoacetic ester. Hydrolysis of ethyl tetrachloro-2-pyridylacetoacetate gives 3,4,5,6-tetrachloro-2-pyridylacetic acid rather than the corresponding acetone derivative.

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Literature cited

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, 252660, Kiev

    S. D. Moshchitskii, A. F. Pavlenko & G. A. Zalesskii

Authors
  1. S. D. Moshchitskii
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  2. A. F. Pavlenko
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  3. G. A. Zalesskii
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 950–953, July, 1978.

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Moshchitskii, S.D., Pavlenko, A.F. & Zalesskii, G.A. Reaction of pent achloropyridine with sodioacetoacetic ester. Chem Heterocycl Compd 14, 765–769 (1978). https://doi.org/10.1007/BF00471647

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  • DOI: https://doi.org/10.1007/BF00471647

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