Advertisement

Chemistry of Heterocyclic Compounds

, Volume 14, Issue 7, pp 765–769 | Cite as

Reaction of pent achloropyridine with sodioacetoacetic ester

  • S. D. Moshchitskii
  • A. F. Pavlenko
  • G. A. Zalesskii
Article
  • 55 Downloads

Abstract

Ethyl tetrachloro-4-pyridylacetoacetates and tetrachloro-2-pyridylacetoacetates were synthesized by reaction of pentachloropyridine with sodioacetoacetic ester. Hydrolysis of ethyl tetrachloro-2-pyridylacetoacetate gives 3,4,5,6-tetrachloro-2-pyridylacetic acid rather than the corresponding acetone derivative.

Keywords

Ester Hydrolysis Ethyl Acetone Organic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    S. D. Moshchitskii, G. A. Zalesskii, A. F. Pavlenko, and Ya. N. Ivashchenko, Khim. Geterotsikl. Soedin., No. 6, 791 (1970).Google Scholar
  2. 2.
    S. D. Moshchitskii, E. S. Dubinskaya, and A. F. Pavlenko, Ukr. Khim. Zh., 40, 744 (1974).Google Scholar
  3. 3.
    Houben-Weyl, Methoden der Organischen Chemie, Geor Thieme Verlag, Stuttgart (1952–1958).Google Scholar
  4. 4.
    R. W. Taft, J. Am. Chem. Soc., 75, 4231 (1953).Google Scholar
  5. 5.
    K. H. Meyer, Ber., 45, 2855 (1912).Google Scholar
  6. 6.
    Yu. A. Zhdanov and V. I. Minkin, Correlation Analysis in Organic Chemistry [in Russian], Izd. Rostovsk. Univ. (1966), p. 312.Google Scholar
  7. 7.
    I. F. Mikhailova and V. A. Barkhash, Zh. Obshch. Khim., 37, 2792 (1967).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • S. D. Moshchitskii
    • 1
  • A. F. Pavlenko
    • 1
  • G. A. Zalesskii
    • 1
  1. 1.Institute of Organic ChemistryAcademy of Sciences of the Ukrainian SSRKiev

Personalised recommendations