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Chemistry of Heterocyclic Compounds

, Volume 14, Issue 7, pp 752–754 | Cite as

Nucleophilic substitution in iodonium derivatives of indole

  • M. S. Ermolenko
  • V. A. Budylin
  • A. N. Kost
Article

Abstract

3-Indolylphenyliodonium tosylate and trifluoroacetate were synthesized, and their reaction with halide anions was investigated. It is shown that the iodonium grouping is replaced by halogen in all cases. 3-Fluoroindole was synthesized for the first time. The mechanism of the reaction is discussed, and data from the mass spectra of the 3-haloindoles obtained are presented.

Keywords

Mass Spectrum Organic Chemistry Indole Halide Halogen 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • M. S. Ermolenko
    • 1
  • V. A. Budylin
    • 1
  • A. N. Kost
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityMoscow

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