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Chemistry of Heterocyclic Compounds

, Volume 9, Issue 7, pp 841–844 | Cite as

Stereoisomers of 2-methyl-1-thiadecalin

  • E. N. Karaulova
  • L. M. Petrova
  • G. D. Gal'pern
  • A. Yu. Koshevnik
  • E. S. Brodskii
  • I. M. Lukashenko
  • F. V. Kozlova
Article
  • 25 Downloads

Abstract

A mixture of the geometrical isomers of 2-methyl-1-thiadecalin has been separated by a combination of adsorption column chromatography and preparative gas-liquid chromatography. The configuration of each isomer has been established by mass spectrometry and PMR spectrometry with the application of the Auwers-Skita rule.

Keywords

Chromatography Mass Spectrometry Organic Chemistry Column Chromatography Geometrical Isomer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    E. N. Karaulova, V. Sh. Shaikhrazieva, and G. D. Gal'pern, Khim. Geterotsikl. Soedin., 51 (1967).Google Scholar
  2. 2.
    E. N. Karaulova, G. D. Gal'pern, V. Sh. Shaikhrazieva, T. S. Bobruiskaya, and I. V. Cherepanova, in: Physical and Physicochemical Methods of Analyzing Organic Compounds [in Russian], Nauka, Moscow (1970), p. 76.Google Scholar
  3. 3.
    L. N. Stukanova, T. N. Shan'gina, and Al. A. Petrov, Neftekhimiya, 9, 196 (1969).Google Scholar
  4. 4.
    E. N. Karaulova, G. D. Gal'pern, and V. Sh. Shaikhrazieva, Neftekhimiya, 7, 812 (1967).Google Scholar
  5. 5.
    E. N. Karaulova, G. D. Gal'pern, V. D. Nikitina, I. V. Cherepanova, and L. R. Barykina, Neftekhimiya, 12, 104 (1972).Google Scholar
  6. 6.
    I. N. Nazarov, A. I. Kuznetsova, and I. A. Gurvich, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 118 (1948).Google Scholar
  7. 7.
    E. S. Brodskii, R. A. Khmel'nitskii, A. A. Polyakova, and G. D. Gal'pern, Izv. Akad. Nauk SSSR, Ser. Khim., 2188 (1969).Google Scholar
  8. 8.
    H. Budzikiewicz, C. Djerassi, and D. Williams, Interpretation of Mass Spectra of Organic Compounds, Holden-Day, San Francisco (1964).Google Scholar
  9. 9.
    I. M. Lukashenko, E. S. Brodskii, I. A. Musaev, É. Kh. Kurashova, V. G. Lebedevskaya, and P. I. Sanin, Neftekhimiya, 13, 163 (1973).Google Scholar
  10. 10.
    J. Emsley, J. Feeney, and L. Sutcliffe, High Resolution NMR Spectroscopy, Pergamon, Oxford (1965), 1966.Google Scholar
  11. 11.
    E. M. Banas, A. W. Weitkamp, and N. S. Bhacca, Anal. Chem., 38, 1783 (1966).Google Scholar
  12. 12.
    E. L. Eliel and R. O. Hutchins, J. Amer. Chem. Soc., 91, 2703 (1969).Google Scholar
  13. 13.
    J. Gelan and M. Antennis, Bull. Soc. Chim. Belges, 79, 313 (1970).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • E. N. Karaulova
    • 1
  • L. M. Petrova
    • 1
  • G. D. Gal'pern
    • 1
  • A. Yu. Koshevnik
    • 1
  • E. S. Brodskii
    • 1
  • I. M. Lukashenko
    • 1
  • F. V. Kozlova
    • 1
  1. 1.Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow

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